Title of article
Highly selective syn glycolate aldol reactions with boron enolates of Masamune norephedrine esters
Author/Authors
Andrus، نويسنده , , Merritt B and Soma Sekhar، نويسنده , , B.B.V and Turner، نويسنده , , Timothy M and Meredith، نويسنده , , Erik L، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
5
From page
7197
To page
7201
Abstract
Boron enolates of norephedrine-based glycolate esters reacted with various aldehydes to produce syn aldol products in high yield and selectivity. The outcome is consistent with a Z enolate reacting through a closed transition state with reversal of the enolate facial selectivity relative to the propionate enolates.
Keywords
aldol reaction , Enolate , glycolate , diastereoselection , Diols
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1647562
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