Title of article
Preparation of a crown-ether-modified lophine peroxide as a guest-sensitive novel chemiluminophore and modulation of its chemiluminescence by metal cations
Author/Authors
Okamoto، نويسنده , , Hideki and Owari، نويسنده , , Makoto and Kimura، نويسنده , , Masaru and Satake، نويسنده , , Kyosuke، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
7453
To page
7455
Abstract
A guest-sensitive chemiluminophore, a novel crown-ether-modified lophine peroxide 1, has been prepared, and its chemiluminescent behavior has been investigated in the presence of alkaline and alkaline earth metal cations. In the presence of Na+, the λmax of the chemiluminescence of peroxide 1 was blue-shifted (505 nm) compared to the case without a metal cation (566 nm). The chemiluminescent intensity was enhanced by addition of Na+ while that of Mg2+ decreased the intensity.
Keywords
Chemiluminescence , chemiluminescent ionophore , aza crown ether , lophine peroxide
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1647704
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