Title of article :
Mechanistic consideration of Ti(salen)-catalyzed asymmetric sulfoxidation
Author/Authors :
Saito، نويسنده , , Bunnai and Katsuki، نويسنده , , Tsutomu، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
Asymmetric sulfoxidation using di-μ-oxo Ti(salen) complex 2 as the catalyst was revealed to proceed through C2-symmetric Ti(salen) complex 6 and peroxo Ti(salen) complex 4 in sequence on the basis of MS and NMR studies of the complexes and the observation of positive non-linear effect.
Keywords :
Non-linear effect , Asymmetric catalysis , Ti(salen) , di-?-oxo Ti(salen) , cis-? structure , Sulfoxidation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
