Author/Authors :
Gerald M. and Dِbler، نويسنده , , Christian and Mehltretter، نويسنده , , Gerald M and Sundermeier، نويسنده , , Uta and Eckert، نويسنده , , Markus and Militzer، نويسنده , , Hans-Christian and Beller، نويسنده , , Matthias، نويسنده ,
Abstract :
The osmium-catalyzed oxidation of alcohols with molecular oxygen to give aldehydes in good to excellent yields has been developed. Best results are obtained by using a buffered two-phase system with a constant pH of 10.4. Under optimized reaction conditions a remarkable catalyst productivity (TON up to 16600) is observed.
Keywords :
alcohols , Oxidation , Oxygen , Aldehydes , osmium
