Title of article
1,3-Bis(4-methoxyphenyl)cyclohexane-1,3-diyl cation radical: divergent reactivity depending upon electron-transfer conditions
Author/Authors
Ikeda، نويسنده , , Hiroshi and Hoshi، نويسنده , , Yosuke and Miyashi، نويسنده , , Tsutomu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
8485
To page
8488
Abstract
1,3-Bis(4-methoxyphenyl)cyclohexane-1,3-diyl cation radical gives 1,5-bis(4-methoxyphenyl)bicyclo[3.1.0]hexane through 1,3-bis(4-methoxyphenyl)cyclohexane-1,3-diyl when generated by photoinduced electron transfer, but gives 4,4″-dimethoxy-m-terphenyl when generated by using one-electron oxidant, demonstrating its divergent reactivity depending upon the electron-transfer conditions employed.
Keywords
Reaction Mechanism , Electron transfer , back electron transfer , photochemistry , cation radical
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1648335
Link To Document