• Title of article

    Direct construction of a quaternary carbon center utilizing an organosamarium reagent

  • Author/Authors

    Li، نويسنده , , Zhifang and Zhang، نويسنده , , Yongmin، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    8507
  • To page
    8510
  • Abstract
    Direct geminal diallylation of lactams and acyclic amides containing an NH bond has been achieved in the presence of allylsamarium bromide. By applying this method, quaternary carbons have been constructed, and 2,2-diallylated nitrogen heterocycles and diallylated amides were synthesized in moderate to good yields under mild conditions.
  • Keywords
    Allyl bromide , acyclic amides , lactams , 2 , 2-diallylated nitrogen heterocycles , diallylated amides , reductive diallylation , Samarium
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1648353