Title of article
Direct construction of a quaternary carbon center utilizing an organosamarium reagent
Author/Authors
Li، نويسنده , , Zhifang and Zhang، نويسنده , , Yongmin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
8507
To page
8510
Abstract
Direct geminal diallylation of lactams and acyclic amides containing an NH bond has been achieved in the presence of allylsamarium bromide. By applying this method, quaternary carbons have been constructed, and 2,2-diallylated nitrogen heterocycles and diallylated amides were synthesized in moderate to good yields under mild conditions.
Keywords
Allyl bromide , acyclic amides , lactams , 2 , 2-diallylated nitrogen heterocycles , diallylated amides , reductive diallylation , Samarium
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1648353
Link To Document