Title of article
Synthesis of (+)-epiepoformin using the base-catalyzed Diels–Alder reaction of 3-hydroxy-2-pyrone
Author/Authors
Shimizu، نويسنده , , Hideki and Okamura، نويسنده , , Hiroaki and Yamashita، نويسنده , , Naomi and Iwagawa، نويسنده , , Tetsuo and Nakatani، نويسنده , , Munehiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
8649
To page
8651
Abstract
Asymmetric total synthesis of (+)-epiepoformin was achieved in short steps using the base-catalyzed asymmetric Diels–Alder (DA) reaction of 3-hydroxy-2-pyrone with chiral acrylate. Since the synthesis produced Ogasawaraʹs intermediate, it is also presented as a formal synthesis of (−)-theobroxide.
Keywords
asymmetric synthesis , cyclohexene oxides , Base-catalyst , Diels–Alder reaction
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1648490
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