Title of article :
Formation of 1,2,4-trioxolanes via 9,10-dicyanoanthracene(DCA)-sensitized photo-oxygenation of 2,2-diaryl-3-(2,2-diarylvinyl)oxiranes
Author/Authors :
Kamata، نويسنده , , Masaki and Komatsu، نويسنده , , Ken-ichi and Akaba، نويسنده , , Ryoichi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
9,10-Dicyanoanthracene-sensitized photo-oxygenation of 2,2-diaryl-3-(2,2-diarylvinyl)oxiranes 3 in acetonitrile did not afford the corresponding 1,2,4-trioxepines 4, but 1,2,4-trioxolanes 7. The structural assignment of 7 was reported, and the mechanism of the formation of 7 was proposed.
Keywords :
1 , 2 , vinyl oxirane , 9 , 10-Dicyanoanthracene , Electron transfer , Reaction Mechanism , photo-oxygenation , 4-Trioxolane
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
