Title of article :
Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide–imine complexes
Author/Authors :
Takaki، نويسنده , , Ken and Sonoda، نويسنده , , Kentaro and Kousaka، نويسنده , , Takeshi and Koshoji، نويسنده , , Go and Shishido، نويسنده , , Tetsuya and Takehira، نويسنده , , Katsuomi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
Divalent lanthanide–imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl- and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, under similar conditions.
Keywords :
double silylation , olefins , Conjugated dienes , lanthanide catalyst , Hydrosilylation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
