The synthesis of a key intermediate en route to gelsemine: a program based on intramolecular displacement of the carbonoxygen bond of a strategic oxetane
Author/Authors :
Ng، نويسنده , , Fay W and Lin، نويسنده , , Hong and Tan، نويسنده , , Qiang and Danishefsky، نويسنده , , Samuel J، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Pages :
4
From page :
545
To page :
548
Abstract :
The synthesis of key intermediate 30 en route to gelsemine has been accomplished from known aldehyde 10 via oxetane 19 featuring stereospecific Claisen rearrangement and Lewis acid-catalyzed oxetane ring opening.
