Author/Authors :
Cabianca، نويسنده , , E and Chéry، نويسنده , , F and Rollin، نويسنده , , P and Tatibouët، نويسنده , , A and De Lucchi، نويسنده , , O، نويسنده ,
Abstract :
A general selective synthesis of β-, γ- and δ-hydroxyethenyl ethers, a class of compounds containing two mutually reactive functionalities positioned at an interacting distance, is based on the reaction of diols with 1,2-bis-(phenylsulfonyl)ethylene (BPSE) followed by reductive elimination of the resulting β-phenylsulfonyl acetals with sodium amalgam.