Author/Authors :
Miller، نويسنده , , Ross A. and Smith، نويسنده , , Randi M. and Karady، نويسنده , , Sandor and Reamer، نويسنده , , Robert A.، نويسنده ,
Abstract :
General, highly selective silylation conditions for the ambident oxazole anion (isocyano enolate) have been found. The chemoselectivity between O-silylation and C-silylation changed from <1:99 to >99:1 upon switching from R3SiCl to R3SiOTf.