Impedance of Al-substituted α-nickel hydroxide electrodes

Al-substituted α-nickel hydroxide were used as active materials in pasted nickel hydroxide electrodes for rechargeable alkaline batteries. The electrochemical impedance spectra of α-nickel hydroxide electrodes with different Al contents were measured. An equivalent circuit model was applied to simulate the experimental results. Some equivalent circuit parameters for different electrodes were determined. The reason why the α-nickel hydroxide electrode with 25% Al shows a better performance was discussed using these parameters.