Title of article :
Synthesis, catalytic activity and redox properties of palladium(0) complexes with 15-membered triolefinic macrocyclic ligands containing one, two or three ferrocenyl groups
Author/Authors :
Llobet، نويسنده , , Antoni and Masllorens، نويسنده , , Ester and Moreno-Ma?as، نويسنده , , Marcial and Pla-Quintana، نويسنده , , Anna and Rodr??guez، نويسنده , , Montserrat and Roglans، نويسنده , , Anna، نويسنده ,
Abstract :
A series of 15-membered triolefinic macrocycles containing ferrocenyl groups and their palladium(0) complexes have been synthesized and characterized. Their catalytic activity has been demonstrated in Suzuki-type cross-coupling and in the Heck reaction. Their redox properties have been investigated by means of cyclic voltammetry.
Keywords :
Macrocycles , Ferrocene , triene palladium(0) complexes , Catalysis