Author/Authors :
Antonio Garrido Montalban، نويسنده , , Antonio and Herrera، نويسنده , , Antonio J. and Johannsen، نويسنده , , Jes and Beck، نويسنده , , Josephine and Godet، نويسنده , , Thomas and Vrettou، نويسنده , , Marianna and White، نويسنده , , Andrew J.P. and Williams، نويسنده , , David J.، نويسنده ,
Abstract :
Dipyrromethane-2,10-dicarboxylates have been prepared. While oxidation and subsequent reaction of 5b with BF3·OEt2 yields the corresponding complex 10, ring-closing metathesis of 5d using (NHC)(PCy3)(Cl)2RuCHPh 7 results in the novel hybrid macrocycle 8. The structure of 10 has been unequivocally established by an X-ray crystallographic study.
Keywords :
complexes , Dipyrromethanes , dipyrromethenes , ring-closing metathesis , Macrocycles