Title of article
Hydroformylation of cyclopentenes, novel strategy for total synthesis of carba-d-fructofuranose
Author/Authors
Mohindra Seepersaud، نويسنده , , Mohindra and Kettunen، نويسنده , , Mika and Abu-Surrah، نويسنده , , Adnan S and Repo، نويسنده , , Timo and Voelter، نويسنده , , Wolfgang and Al-Abed، نويسنده , , Yousef، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
1793
To page
1795
Abstract
Carba-d-fructofuranose (2a) was synthesized in 3 steps from cyclopentene 3. Compound 3 was prepared in 90% yield from commercially available 2,3,5-tri-O-benzyl-d-arabinose. The C-5 hydroxylmethyl unit was incorporated into 3 via hydroformylation using Wilkinsonʹs catalyst. Reduction and hydrogenation afforded carba-d-fructofuranose (2a).
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1650332
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