Title of article
Three-component synthesis of 2-haloalk-2(Z)-en-1-ols via tandem haloalkylidenation–aldehyde addition
Author/Authors
Baati، نويسنده , , Rachid and Barma، نويسنده , , D.K. and Falck، نويسنده , , J.R. and Mioskowski، نويسنده , , Charles، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
2179
To page
2181
Abstract
Cr(II)-induced condensation of CCl4 or CBr4 with an aldehyde stereospecifically generates an (E)-α-haloalkylidene chromium carbenoid which adds in situ to a second equivalent of aldehyde furnishing 2-haloalk-2(Z)-en-1-ols in high yield.
Keywords
Chromium , vinylation , Alkenylation , alcohols , stereocontrol
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1650610
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