Title of article :
A versatile synthesis of 2-haloalk-2(Z)-en-1-ols and 1-chloro-1(Z)-alkenes from trichloromethylcarbinols
Author/Authors :
Baati، نويسنده , , Rachid and Barma، نويسنده , , D.K. and Falck، نويسنده , , J.R. and Mioskowski، نويسنده , , Charles، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
CrCl2 converts trichloromethylcarbinols under mild conditions to (E)-α-haloalkylidene chromium carbenoids which add to aldehydes or are quenched with water affording 2-haloalk-2(Z)-en-1-ols and 1-chloro-1(Z)-alkenes, respectively, in high yield.
Keywords :
Chromium , Alkenylation , vinylation , stereocontrol , alcohols
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
