• Title of article

    Regio- and stereoselective cyclopropanation of functionalised dienes. Novel methodology for the synthesis of vinyl- and divinyl-cyclopropanes

  • Author/Authors

    Markَ، نويسنده , , Istvلn E. and Giard، نويسنده , , Thierry and Sumida، نويسنده , , Shinichi and Gies، نويسنده , , Anne-Elisabeth، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    2317
  • To page
    2320
  • Abstract
    Dienes, bearing an electron-withdrawing substituent at C-1, are cyclopropanated regio- and stereoselectively at the CC double bond proximal to this electron-withdrawing group. The highest selectivity is observed in the case of dienylboronates. The cyclopropanation of these substrates affords almost exclusively the synthetically useful 1-boronato-2-vinyl-cyclopropanes.
  • Keywords
    Cyclopropanes , PALLADIUM , vinylcyclopropanes , Suzuki coupling , dienylboronates
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1650704

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1650704