Author/Authors :
Viktor V. Zhdankin، نويسنده , , Viktor V. and Maydanovych، نويسنده , , Olena and Herschbach، نويسنده , , Jon and Bruno، نويسنده , , Jessica and Matveeva، نويسنده , , Elena D. and Zefirov، نويسنده , , Nikolai S.، نويسنده ,
Abstract :
New triphenylphosphorane-derived phenyliodonium triflates and tosylates were prepared by the reaction of the appropriate iodosobenzene sulfonate with stabilized phosphonium ylides. Structure of the triflate derivative was determined by a single-crystal X-ray analysis. These compounds represent a potentially useful class of reagents that combine in one molecule synthetic advantages of a phosphonium ylide and an iodonium salt.
Keywords :
hypervalent iodine , Phosphonium , X-ray crystallography , Iodonium