Title of article :
Dearomatisation of 1- and 2-cyanonaphthalene through nucleophilic conjugate addition
Author/Authors :
And?jar S?nchez، نويسنده , , Carmen M. and Iglesias، نويسنده , , Ma? José and L?pez Ortiz، نويسنده , , Fernando، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Conjugate nucleophilic addition of organolithium compounds to 1- and 2-cyanonaphthalene is described for the first time. The dearomatisation is carried out in the presence of HMPA and leads to functionalised dihydronaphthalenes. The nucleophiles used include simple lithium reagents as well as phosphorus-stabilised anions.
Keywords :
dihydronaphthalenes , cyanonaphthalene , conjugate addition , phosphine borane anions , dearomatisation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
