Title of article
Hetero-Cope rearrangement for the synthesis of potassium 5-tert-butyl-2-(tert-butyl-aminoxy)-benzoate, a highly water-soluble stable free radical
Author/Authors
Marx، نويسنده , , Lucien and Rassat، نويسنده , , André، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
2
From page
2613
To page
2614
Abstract
The hetero-Cope rearrangement of 4-tert-butyl-phenyl-tert-butylhydroxylamine provides an easy access to the corresponding ortho-bromoaniline, converted to the new highly water-soluble nitroxide, potassium 5-tert-butyl-2-(tert-butyl-aminoxy)-benzoate. The parent carboxylic acid was found to be very persistent in water at pH 1.
Keywords
hydroxylamines , carboxylate , hetero-Cope rearrangement , decomposition , Nitroxides
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1650910
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