Author/Authors :
Brinksma، نويسنده , , Jelle and Schmieder، نويسنده , , Lizette and van Vliet، نويسنده , , Gerbert and Boaron، نويسنده , , Rob and Hage، نويسنده , , Ronald and De Vos، نويسنده , , Dirk E and Alsters، نويسنده , , Paul L and Feringa، نويسنده , , Ben L، نويسنده ,
Abstract :
The use of [Mn2O3(tmtacn)2](PF6)2 (tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane) in combination with glyoxylic acid methylester methyl hemiacetal (GMHA) results in a highly active and hydrogen peroxide efficient catalyst for the epoxidation of olefins as well as the first homogeneous catalytic cis-dihydroxylation system with H2O2 and with turnover numbers up to 420.
Keywords :
Hydrogen peroxide , cis-diols , epoxides , Oxidation , Manganese
