Title of article :
Synthesis of 11,12-disubstituted 9,10-anthraquinodimethanes: the first dehydroxylation reaction by active magnesium
Author/Authors :
Shah، نويسنده , , Shaheen M.I and Kuroda، نويسنده , , Shigeyasu and Oda، نويسنده , , Mitsunori and Tanaka، نويسنده , , Tokiko and Miyatake، نويسنده , , Ryuta and Izawa، نويسنده , , Mayumi، نويسنده ,
Abstract :
The reaction of 9,10-diformylanthracene with Grignard reagents gave 11,12-disubstituted 9,10-anthraquinonemethane (1) in quantitative to excellent yields. The formation of these quinodimethanes caused by the active magnesium generated from the Grignard reagents was revealed.