Title of article
Preparation of a fluorous chiral BINAP and application to an asymmetric Heck reaction
Author/Authors
Nakamura، نويسنده , , Yutaka and Takeuchi، نويسنده , , Seiji and Zhang، نويسنده , , Songlin and Okumura، نويسنده , , Kazuo and Ohgo، نويسنده , , Yoshiaki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
3053
To page
3056
Abstract
Fluorous chiral BINAP ((R)-F13BINAP) was prepared and was applied to an asymmetric Heck reaction. The enantioselectivity was similar in BTF homogeneous system (90% ee) to that of the original non-fluorous reaction and marginally higher in benzene and FC-72 biphasic system (93% ee) than that of the original non-fluorous one.
Keywords
Fluorine and compounds , Perfluoroalkyl compounds , Heck reaction , Asymmetric reactions
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1651241
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