Author/Authors :
Nakamura، نويسنده , , Yutaka and Takeuchi، نويسنده , , Seiji and Zhang، نويسنده , , Songlin and Okumura، نويسنده , , Kazuo and Ohgo، نويسنده , , Yoshiaki، نويسنده ,
Abstract :
Fluorous chiral BINAP ((R)-F13BINAP) was prepared and was applied to an asymmetric Heck reaction. The enantioselectivity was similar in BTF homogeneous system (90% ee) to that of the original non-fluorous reaction and marginally higher in benzene and FC-72 biphasic system (93% ee) than that of the original non-fluorous one.
Keywords :
Fluorine and compounds , Perfluoroalkyl compounds , Heck reaction , Asymmetric reactions
