Author/Authors :
Blake، نويسنده , , Michael E and Jones Jr.، نويسنده , , Maitland and Zheng، نويسنده , , Fengmei and Moss، نويسنده , , Robert A، نويسنده ,
Abstract :
In contrast to photolysis or thermal decomposition in solution, which is dominated by ionic reactions, flash vacuum pyrolysis of alkylchlorodiazirines in the gas phase generates radicals. The cyclopropylcarbinyl system is re-examined and the 1-norbornylcarbinyl system is studied for the first time.