• Title of article

    A new chiral ruthenium complex for catalytic asymmetric cyclopropanation

  • Author/Authors

    Tang، نويسنده , , Wenjun and Hu، نويسنده , , Xinquan and Zhang، نويسنده , , Xumu Zhang، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    3075
  • To page
    3078
  • Abstract
    A new chiral ruthenium complex 6, featured with an N,O-mixed polydentate ligand, was synthesized and characterized. This ruthenium complex showed high efficiency in catalytic cyclopropanations of alkenes with diazoacetates. High trans/cis selectivity and enantioselectivity (up to 96%) were achieved with the readily accessible ethyl diazoacetate as the reagent.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1651255