Title of article
Reinvestigation of the fluoride-triggered condensation of allyltrimethylsilane with cinnamonitrile: ‘abnormal Sakurai’ and sequential ‘abnormal Sakurai’–Michael–Thorpe Ziegler side reactions
Author/Authors
Keller، نويسنده , , Laurent and Dumas، نويسنده , , Françoise and Pizzonero، نويسنده , , Mathieu and dʹAngelo، نويسنده , , Jean and Morgant، نويسنده , , Georges and Nguyen-Huy، نويسنده , , Dung، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
3225
To page
3228
Abstract
Together with the expected 1,4-adduct, three by-products are generated in the fluoride-triggered condensation of allyltrimethylsilane with cinnamonitrile: the 1,3 adduct, an acyclic dinitrile and a cyclopentenaminonitrile issuing, respectively, from ‘abnormal Sakurai’, ‘abnormal Sakurai’–Michael and ‘abnormal Sakurai’–Michael–Thorpe Ziegler side reactions.
Keywords
Sakurai reactions , Mechanisms , Thorpe and Thorpe–Ziegler reactions , Michael reactions , Rearrangements
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1651361
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