Author/Authors :
Simonneaux، نويسنده , , Gérard and De Montigny، نويسنده , , Frédéric and Paul-Roth، نويسنده , , Christine and Gulea، نويسنده , , Mihaela and Masson، نويسنده , , Serge، نويسنده ,
Abstract :
Catalytic systems derived from Ru(CO)porphyrins are extremely efficient at converting styrene and diisopropyl diazomethyl phosphonate to cyclopropyl phosphonate esters in high yields and with high stereoselectivity; a monocarbene complex Ru(TPP)(CH{P(O)(OiPr)2}) has been isolated as a possible catalytically active species.