Title of article
Totally diastereoselective synthesis of a new chiral quinoline diazaphospholidine ligand and its derivatives
Author/Authors
Delapierre، نويسنده , , Guillaume and Achard، نويسنده , , Mathieu and Buono، نويسنده , , Gérard، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
4025
To page
4028
Abstract
QUIPHOS-PN5, a new stable P,N ligand with a stereogenic phosphorus centre was synthesised in two steps from 8-bromoquinoline (61% yield). Its structure and its bidentate chelating ability was confirmed by the X-ray structure of a palladium(II) complex with this ligand. P(V) derivatives of QUIPHOS-PN5 were then easily obtained in excellent yields (85–100%).
Keywords
N ligand , Phosphine oxide , Palladium complex , phosphine sulphide , Chiral bidentate P , iminophosphorane
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1651937
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