Title of article :
Synthesis of chiral 4-nitrophenyl alkyl methylphosphonothioates: BF3·Et2O-catalyzed alcoholysis of phosphonamidothioates
Author/Authors :
Reddy، نويسنده , , Putta Mallikarjuna and Kovach، نويسنده , , Ildiko M، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Facile and highly enantioselective synthesis of 4-nitrophenyl alkyl methylphosphonothioates 5a–f was achieved in high yields via BF3·Et2O-catalyzed alcoholysis of resolved phosphonamidothioates 4a and 4b.
Keywords :
BF3·Et2O-catalyzed alcoholysis , asymmetric synthesis , phosphonamidothioates , (S)-(?)-?-methylbenzylamine
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
