Manganese (II) selective PVC based membrane sensor using a Schiff base

N,N′,N″,N′′′-1,5,8,12-tetraazadodecane-bis(salicylaldiminato)(H2L) has been used as ionophore for preparing Mn2+ selective sensor. Membranes of different composition with regard to ratio of H2L:PVC:NPOE:NaTPB have been prepared and investigated. The best performance was obtained with the membrane of composition 10:150:150:10 (H2L:PVC:NPOE:NaTPB) (w/w; mg). This membrane generated linear potential response in the concentration range of 5.0 × 10−6 to 1.0 × 10−1 M with a Nernstian slope of 30.0 mV/decade of activity and fast response time (10 s). Hydrogen ion does not effect to the performance of sensor in the pH range 3.0–6.5. The sensor was found to be sufficient selective for Mn2+ over a number of alkali, alkaline and heavy metal ions and could therefore be used for the determination of manganese in various samples by direct potentiometry.