• Title of article

    Efficient and clean synthesis of N-alkyl carbamates by transcarboxylation and O-alkylation coupled reactions using a DBU–CO2 zwitterionic carbamic complex in aprotic polar media

  • Author/Authors

    Pérez، نويسنده , , Eduardo R and da Silva، نويسنده , , Michele Odnicki and Costa، نويسنده , , Vanessa C and Rodrigues-Filho، نويسنده , , Ubirajara P and Franco، نويسنده , , Douglas W، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    3
  • From page
    4091
  • To page
    4093
  • Abstract
    N-Alkyl carbamates were obtained with good to excellent yields by clean and mild transcarboxylation of several amines with the previously synthesized DBU–CO2 complex and subsequent O-alkylation. Transcarboxylation was found to be selective, as only carbamate was formed from 1-hydroxy-2-aminobutanol.
  • Keywords
    Carbon dioxide , DBU–CO2 , transcarboxylation , N-alkyl carbamates
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1651987