Title of article :
The reactivity of 3-methyl-4-nitro-5-styrylisoxazole with some bis-enolisable ketones
Author/Authors :
Adamo، نويسنده , , Mauro F.A. and Chimichi، نويسنده , , Stefano and De Sio، نويسنده , , Francesco and Donati، نويسنده , , Donato and Sarti-Fantoni، نويسنده , , Piero، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Pages :
4
From page :
4157
To page :
4160
Abstract :
The expected Michael adducts and spiroisoxazolines are obtained from the reaction between 3-methyl-4-nitro-5-styrylisoxazole and bis-enolisable ketones. Contrary to reported data, Michael adducts are obtained in good yields only when a substoichiometric amount of base is used, whereas spiroisoxazolines were obtained as the major product when the base is present in a large excess.
Keywords :
diastereoselective reaction , spiroisoxazolines , Michael addition
Journal title :
Tetrahedron Letters
Serial Year :
2002
Journal title :
Tetrahedron Letters
Record number :
1652042
Link To Document :
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