• Title of article

    Chelation-assisted β-alkylation of α,β-unsaturated ketone using Rh(I) catalyst and dialkyl amine

  • Author/Authors

    Jun، نويسنده , , Chul-Ho and Moon، نويسنده , , Choong Woon and Kim، نويسنده , , Young-Min and Lee، نويسنده , , Hyuk and Lee، نويسنده , , Jun Hee، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    4233
  • To page
    4236
  • Abstract
    A new Rh(I)-catalyzed β-alkylation of 4-phenyl-3-buten-2-one (1) was developed by utilizing diethylamine (5a) as a chelation-assistant tool. The key feature of this reaction is the vinyl CH activation driven by amine-assisted cyclometalation to give the β,γ-unsaturated ketones 7 as a major product.
  • Keywords
    C?H activation , Alkylation , ?-Unsaturated ketone , Wilkinson catalyst , ?
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1652087

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1652087