Author/Authors :
Srirattnai، نويسنده , , Kusoomjin and Damronglerd، نويسنده , , Somsak and Omi، نويسنده , , Shinzo and Roengsumran، نويسنده , , Sophon and Petsom، نويسنده , , Amorn and Ma، نويسنده , , Guang-Hui، نويسنده ,
Abstract :
A novel method for the encapsulation of AlCl3 was successfully carried out using an insoluble polymer wall. The polymer wall was formed by the reaction of poly(styrene-co-dimethylaminoethyl methacrylate) and hydrogenated telechelic polybutadiene containing -COOH groups. The encapsulated AlCl3 was used to catalyze the Friedel–Crafts alkylation of benzene with dodecene. The alkylbenzenes were obtained in excellent yields and the encapsulated AlCl3 catalyst was separated by simple filtration.
Keywords :
encapsulated AlCl3 , Friedel–Crafts alkylation , alkylbenzene , hydrogenated telechelic polybutadiene
