Title of article
Sequential alkoxy radical fragmentation–intermolecular allylation in carbohydrate systems
Author/Authors
Mart??n، نويسنده , , Angeles and Pérez-Mart??n، نويسنده , , Inés and Su?rez، نويسنده , , Ernesto، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
4781
To page
4784
Abstract
The C-radical originated by β-fragmentation of carbohydrate anomeric alkoxy radicals, generated under reductive conditions by treatment of N-phthalimido glycosides with allyltri-n-butyltin/AIBN, may subsequently undergo an intermolecular allylation to give hept-1-enitol derivatives. These compounds can be useful chiral synthons for the synthesis of polyhydroxylated compounds.
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1652448
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