• Title of article

    Alkylidenecarbene insertion at anomeric CH bonds. Synthesis of 3-deoxy-d-arabino-2-heptulosonic acid (DAH) and 3-deoxy-d-manno-2-octulosonic acid (KDO)

  • Author/Authors

    Wardrop، نويسنده , , Duncan J and Zhang، نويسنده , , Wenming، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    3
  • From page
    5389
  • To page
    5391
  • Abstract
    A novel method for the homologation of glycals to the corresponding 3-deoxy-2-ulosonic acids, based on the [1,5]-CH bond insertion of alkylidenecarbenes, is presented. The application of this approach is illustrated through the synthesis of 3-deoxy-d-arabino-2-heptulosonic acid (DAH) and 3-deoxy-d-manno-2-octulosonic acid (KDO).
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1652873