Title of article
Alkylidenecarbene insertion at anomeric CH bonds. Synthesis of 3-deoxy-d-arabino-2-heptulosonic acid (DAH) and 3-deoxy-d-manno-2-octulosonic acid (KDO)
Author/Authors
Wardrop، نويسنده , , Duncan J and Zhang، نويسنده , , Wenming، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
5389
To page
5391
Abstract
A novel method for the homologation of glycals to the corresponding 3-deoxy-2-ulosonic acids, based on the [1,5]-CH bond insertion of alkylidenecarbenes, is presented. The application of this approach is illustrated through the synthesis of 3-deoxy-d-arabino-2-heptulosonic acid (DAH) and 3-deoxy-d-manno-2-octulosonic acid (KDO).
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1652873
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