Title of article :
Stereoselective alkane hydroxylations by metal salts and m-chloroperbenzoic acid
Author/Authors :
Nam، نويسنده , , Wonwoo and Ryu، نويسنده , , Ju-Yeon and Kim، نويسنده , , Inwoo and Kim، نويسنده , , Cheal، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Simple metal (M=Mn, Fe, Co) perchlorates associated with m-chloroperbenzoic acid are able to conduct stereoselective alkane hydroxylations via a mechanism involving metal-based oxidants; the catalytic activity of the metal salts is in the order of Co(ClO4)2>Mn(ClO4)2>Fe(ClO4)2.
Keywords :
Alkane hydroxylation , Catalysis , m-chloroperbenzoic acid , biomimetic , Metal perchlorate , Monooxygenases
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
