Title of article
Titanocene(II)-promoted reactions of thioacetals with ethylene: selective formation of terminal olefins with one- or two-carbon homologation
Author/Authors
Tsubouchi، نويسنده , , Akira and Nishio، نويسنده , , Emi and Kato، نويسنده , , Yoshiko and Fujiwara، نويسنده , , Tooru and Takeda، نويسنده , , Takeshi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
5755
To page
5758
Abstract
Thioacetals are selectively transformed into two types of terminal olefins, one with one-carbon homologation and the other with two-carbon homologation, by treatment with a titanocene(II) species under ethylene. The mode of the reaction is controlled by changing the ligands coordinated to titanocene(II).
Keywords
Carbene complexes , ?-Elimination , metathesis , terminal olefins , titanocene(II)
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1653117
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