Title of article :
Indium-mediated allylation reaction of difluoroacetyltrialkylsilanes in aqueous media
Author/Authors :
Chung، نويسنده , , Woo Jin and Higashiya، نويسنده , , Seiichiro and Welch، نويسنده , , John T، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Indium-mediated allylations of difluoroacetyltrialkylsilanes in aqueous media give homoallylic alcohols exclusively. The common Brook rearrangement C- to O-silyl group migration is totally suppressed with no detectable formation of enol silyl ethers. The influence of water on the allylation reaction is also described.
Keywords :
allylation , Homoallylic alcohol , Enol silyl ether , Indium , Brook rearrangement , difluoroacetyltrialkylsilane
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
