Author/Authors :
Phutdhawong، نويسنده , , Weerachai and Pyne، نويسنده , , Stephen G. and Baramee، نويسنده , , Apiwat and Buddhasukh، نويسنده , , Duang and Skelton، نويسنده , , Brian W. and White، نويسنده , , Allan H.، نويسنده ,
Abstract :
A synthesis of (±) epipentenomycin I and III is reported from a regioselective epoxidation of racemic 3-hydroxy- and 3-acetoxy-2-methylene-4-cyclopentenone, respectively, with dimethyldioxirane followed by hydrolytic ring-opening of the resulting epoxide.
Keywords :
epoxide hydrolysis , epoxidation , Dimethyldioxirane , epipentenomycin I and III
