Title of article :
Formation of pyrrolidines by the titanocene(II)-promoted intramolecular reaction of N-[3,3-bis(phenylthio)propyl]anilides
Author/Authors :
Takeda، نويسنده , , Takeshi and Saito، نويسنده , , Jun and Tsubouchi، نويسنده , , Akira، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
The reaction of anilides with the titanium carbene complexes generated by the desulfurization of thioacetals with the titanocene(II) species Cp2Ti[P(OEt)3]2 produced the corresponding enamines. Unusual formation of pyrrolidines was observed when N-[3,3-bis(phenylthio)propyl]anilides were treated with the titanocene(II) reagent.
Keywords :
Pyrrolidines , titanocene(II) , carbonyl olefination , cyclization , enamines
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
