Author/Authors :
Richel، نويسنده , , Aurore and Delfosse، نويسنده , , Sébastien and Cremasco، نويسنده , , Cédric and Delaude، نويسنده , , Lionel and Demonceau، نويسنده , , Albert and Noels، نويسنده , , Alfred F، نويسنده ,
Abstract :
The catalytic activity of ruthenium-p-cymene complexes bearing N-heterocyclic carbene ligands in atom transfer radical addition (ATRA) or polymerisation (ATRP) strongly depends on the substituents of the carbene ligand, thereby providing a nice illustration of the importance of organometallic engineering and ligand fine tuning in homogeneous catalysis.
Keywords :
radicals and radical reactions , olefins , ruthenium and compounds , Catalysis
