Title of article
Ti(IV)/BINOL-catalyzed asymmetric aldol reaction of a masked acetoacetic ester: pronounced influence of catalyst concentration on nonlinear effects
Author/Authors
De Rosa، نويسنده , , Margherita and Acocella، نويسنده , , Maria Rosaria and Villano، نويسنده , , Rosaria and Soriente، نويسنده , , Annunziata and Scettri، نويسنده , , Arrigo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
6087
To page
6090
Abstract
Initial concentration of enantioenriched or enantiopure catalysts proved to be an important factor for the achievement of a more pronounced amplification of eeʹs in the Ti(IV)/BINOL-catalyzed aldol reaction of an O-silyldienolate.
Keywords
Asymmetric aldol reaction , Titanium complex , Binaphthol , Nonlinear effects , O-silyldienolate
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1653829
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