• Title of article

    RhCl3-catalyzed hydroboration of alkenyl nitriles

  • Author/Authors

    Buranov، نويسنده , , Anvar U. and Morrill، نويسنده , , Terence C.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    4
  • From page
    6301
  • To page
    6304
  • Abstract
    RhCl3-promoted hydroboration–oxidation reactions of representative alkenyl nitriles have been carried out. Carbanion of acetonitrile is formed from the carboncarbon heterolytic bond breaking in allyl cyanide during hydroboration. An unexpected process-trimerization of carbanion of acetonitrile has lead to the formation of 4-amino-2,6-dimethylpyrimidine.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1653968