Title of article
RhCl3-catalyzed hydroboration of alkenyl nitriles
Author/Authors
Buranov، نويسنده , , Anvar U. and Morrill، نويسنده , , Terence C.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
6301
To page
6304
Abstract
RhCl3-promoted hydroboration–oxidation reactions of representative alkenyl nitriles have been carried out. Carbanion of acetonitrile is formed from the carboncarbon heterolytic bond breaking in allyl cyanide during hydroboration. An unexpected process-trimerization of carbanion of acetonitrile has lead to the formation of 4-amino-2,6-dimethylpyrimidine.
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1653968
Link To Document