Title of article :
Enantioselective synthesis of sabina ketone
Author/Authors :
Barberis، نويسنده , , Mario and Pérez-Prieto، نويسنده , , Julia، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
Both enantiomers of sabina ketone were efficiently prepared via an easy synthesis of 1-diazo-5-methylene-6-methylheptan-2-one, starting from succinic anhydride, followed by its highly enantioselective cyclization catalyzed by chiral dirhodium(II) compounds having ortho-metalated phosphines as ligands.
Keywords :
sabina ketone , dirhodium(II) compounds , asymmetric synthesis
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
