Title of article
Tandem intermolecular–intramolecular carbolithiation: application to the synthesis of silacyclopentanes
Author/Authors
Wei، نويسنده , , Xudong and Taylor، نويسنده , , Richard J.K. Taylor، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
7143
To page
7146
Abstract
Silacyclopentanes have been prepared from vinyl(homoallyl)silanes or vinyl(homopropargyl)silanes and organolithium reagents by a tandem intermolecular–intramolecular sequence involving a 5-exo cyclisation process. The unexpected stereochemical outcome of the sequence involving a 5-exo-dig cyclisation is rationalised.
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1654615
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