Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides
Author/Authors :
Massa، نويسنده , , Antonio and Malkov، نويسنده , , Andrei V. and Ko?ovsk?، نويسنده , , Pavel and Scettri، نويسنده , , Arrigo، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Pages :
3
From page :
7179
To page :
7181
Abstract :
Allylation of aldehydes with allyltrichlorosilane in the presence of sulfoxides is reported. The use of excess of (R)-methyl-p-tolylsulfoxide resulted in the formation of the corresponding homoallylic alcohols in good yields and moderate enantiomeric excesses.
