Title of article :
A new method for the synthesis of bishydroperoxides based on a reaction of ketals with hydrogen peroxide catalyzed by boron trifluoride complexes
Author/Authors :
Terentev، V. L. نويسنده , , Alexander O. and Kutkin، نويسنده , , Alexander V. and Platonov، نويسنده , , Maxim M. and Ogibin، نويسنده , , Yuri N. and Nikishin، نويسنده , , Gennady I.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
A reaction of cycloalkanone, alkanone and alkyl aryl ketone ketals with H2O2 catalyzed by boron trifluoride etherate and boron trifluoride–methanol complexes was studied. A new versatile method for the synthesis of bishydroperoxides and their derivatives, viz. 1,1′-dihydroperoxyperoxides and 1,2,4,5-tetraoxacyclohexanes, was developed based on this reaction.
Keywords :
acetals , Boron compounds , Catalysts , Peroxidation , Peroxides
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
